| 发明名称 |
SYNTHESIS OF CHALOGEN-CAPPED PI-CONJUGATED POLYMERS |
| 摘要 |
Methods for the preparation of mono- and bis-end-functionalized π-conjugated polymers. In the methods, chalcogens are selectively installed at the polymer terminus or termini. |
| 申请公布号 |
US2015112028(A1) |
申请公布日期 |
2015.04.23 |
| 申请号 |
US201414518951 |
申请日期 |
2014.10.20 |
| 申请人 |
University of Washington through its Center for Commercialization |
发明人 |
Luscombe Christine Keiko;Okamoto Ken |
| 分类号 |
C08G61/12 |
主分类号 |
C08G61/12 |
| 代理机构 |
|
代理人 |
|
| 主权项 |
1. A method for mono-end-functionalizing a poly(arylene) with a chalcogen, comprising:
polymerizing an aryl monomer by reaction with a Grignard reagent and an aryl nickel catalyst to provide an aryl nickel complex-terminated poly(arylene); and treating the aryl nickel complex-terminated poly(arylene) with a chalcogenating agent followed by treatment with an acid to provide a mono-chalcogen-end-functionalized poly(arylene). |
| 地址 |
Seattle WA US |
