| 发明名称 |
ALDEHYDE-SELECTIVE WACKER-TYPE OXIDATION OF UNBIASED ALKENES |
| 摘要 |
This disclosure is directed to methods of preparing organic aldehydes, each method comprising contacting a terminal olefin with an oxidizing mixture comprising:
(a) a dichloro-palladium complex;(b) a copper complex;(c) a source of nitrite;
under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde. |
| 申请公布号 |
US2014316149(A1) |
申请公布日期 |
2014.10.23 |
| 申请号 |
US201414255049 |
申请日期 |
2014.04.17 |
| 申请人 |
CALIFORNIA INSTITUTE OF TECHNOLOGY |
发明人 |
WICKENS ZACHARY K.;MORANDI BILL;GRUBBS ROBERT H.;SKAKUJ KACPER;BRONNER SARAH |
| 分类号 |
C07C45/34;C07C29/132;C07C45/37;C07C249/04;C07C253/00;C07D301/22;C07C45/00 |
主分类号 |
C07C45/34 |
| 代理机构 |
|
代理人 |
|
| 主权项 |
1. A method of preparing organic aldehydes, said method comprising contacting a terminal olefin with an oxidizing mixture comprising:
(a) a dichloro-palladium complex; (b) a copper complex; (c) a source of free nitrite;under aerobic reaction conditions sufficient to convert at least a portion of the terminal olefin to an aldehyde. |
| 地址 |
Pasadena CA US |
