发明名称 METHOD FOR PRODUCING DERIVATIVE OF POLYCYCLIC AROMATIC HYDROCARBON
摘要 PROBLEM TO BE SOLVED: To provide a method for producing a derivative of a polycyclic aromatic hydrocarbon such as alkyl-substituted indene or fluorene, which, even when the derivative has an alkyl substituent, has the reaction yield higher than that of the conventional coupling reaction and the reaction time shorter than that thereof and is useful as a raw material to be used when a metallocene complex is produced.SOLUTION: In the method for producing the derivative of the polycyclic aromatic hydrocarbon, an indene compound (A-1) or a fluorene compound (A-2) is reacted with a specific alkyl group-substituted boron compound (B) to produce a specific alkyl-substituted indene derivative or a specific alkyl-substituted fluorene derivative. A specific phosphorus compound (D) and a palladium catalyst (D) are used as a reaction catalyst, and the reaction is performed in the presence of a fluoride inorganic base (E).
申请公布号 JP2014196274(A) 申请公布日期 2014.10.16
申请号 JP20130073395 申请日期 2013.03.29
申请人 MITSUI CHEMICALS INC 发明人 TANAKA YOICHI
分类号 C07C1/32;C07C13/465;C07C13/567;C08F4/6592 主分类号 C07C1/32
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