发明名称 In situ generation of ruthenium catalysts for olefin metathesis
摘要 Preparing olefins by metathesis reaction comprises providing a reaction mixture comprising at least one olefin, adding a ruthenium compound (I), and adding a Lewis acid or adding a Lewis acid and an anionic, non-coordination salt, and reacting the mixture at 30-140[deg] C, where the reaction takes place without adding an alkyne or alkynol. Preparing olefins by metathesis reaction comprises providing a reaction mixture comprising at least one olefin, adding a ruthenium compound of formula ([RuX2L1xL2y]z) (I), and adding a Lewis acid or adding a Lewis acid and an anionic, non-coordination salt, and reacting the mixture at 30-140[deg] C, where the reaction takes place without adding an alkyne or alkynol. X : anionic ligand; L1 : neutral pi-binding ligand; L2 : neutral electron donor ligand; x : 0 or 1; y : 1-3; and z : 1 or 2.
申请公布号 EP2778154(A1) 申请公布日期 2014.09.17
申请号 EP20130158985 申请日期 2013.03.13
申请人 EVONIK INDUSTRIES AG 发明人 KADYROV,RENAT;LUEBBE,CHRISTA;DUMRATH,ANDREAS;NEUMANN,HELFRIED;BELLER,MATTHIAS
分类号 C07D207/48;C07C6/04;C07C41/18;C07C67/475 主分类号 C07D207/48
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