发明名称 |
A PROCESS FOR DEHYDROCHLORINATING 1,1,1,2-TETRAFLUORO-2-CHLOROPROPANE TO 2,3,3,3-TETRAFLUOROPROPENE IN THE PRESENCE OF AN ALKALI METAL-DOPED MAGNESIUM OXYFLUORIDE CATALYST AND METHODS FOR MAKING THE CATALYST |
摘要 |
A process for making a fluorinated olefin. The process has the step of dehydrochlorinating a hydrochlorofluorocarbon having at least one hydrogen atom and at least one chlorine atom on adjacent carbon atoms in the presence of a catalytically effective amount of a catalyst composition. The catalyst composition is represented by the following: n wt. % MX/M′OyFz, wherein 0<y<1 and 0<z<2 and wherein y+z/2=1; M is an alkali metal ion selected from the group consisting of Li+, Na+, K+, Rb+, and Cs+; X is a halogen ion selected from the group consisting of F−, Cl−, Br−, and I−, M′ is a bivalent metal ion; wherein n is a weight percentage of about 0.05% to about 50% MX based on the total weight of the MX and M′OyFz, and wherein y and z are the mole fractions of oxygen and fluorine in M′OyFz, respectively. There are also methods for making catalyst compositions. |
申请公布号 |
EP2279158(A4) |
申请公布日期 |
2014.07.02 |
申请号 |
EP20090767341 |
申请日期 |
2009.05.28 |
申请人 |
HONEYWELL INTERNATIONAL INC. |
发明人 |
WANG, HAIYOU;TUNG, HSUEH SUNG |
分类号 |
C07C17/23;B01J23/04;B01J27/128;B01J27/138;B01J37/00;B01J37/02;C07C17/25;C07C21/18 |
主分类号 |
C07C17/23 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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