发明名称 |
1,2-BIS(DIALKYLPHOSPHINO)-4,5-(METHYLENEDIOXY)BENZENE DERIVATIVE, METHOD FOR MANUFACTURING SAME, METAL COMPLEX HAVING THIS 1,2-BIS(DIALKYLPHOSPHINO)-4,5-(METHYLENEDIOXY)BENZENE DERIVATIVE AS A LIGAND, AND ASYMMETRIC HYDROGENATION METHOD |
摘要 |
<p>Provided are a novel 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative that forms a metal complex having particularly high asymmetry induction capacity and catalytic activity on ß-dehydroamino acids, a method for manufacturing the same, a metal complex having this 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative as a ligand, and an asymmetric hydrogenation method using this metal complex. A 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative represented by general formula (1). (In the formula, R1 and R2 represent an alkyl group having 1-10 carbon atoms, and R1 and R2 have different numbers of carbon atoms.)</p> |
申请公布号 |
WO2012176830(A1) |
申请公布日期 |
2012.12.27 |
申请号 |
WO2012JP65831 |
申请日期 |
2012.06.21 |
申请人 |
NIPPON CHEMICAL INDUSTRIAL CO., LTD.;ZHANG ZHENFENG;IMAMOTO TSUNEO;TAMURA KEN |
发明人 |
ZHANG ZHENFENG;IMAMOTO TSUNEO;TAMURA KEN |
分类号 |
C07F9/50;C07B53/00;C07C231/18;C07C233/45;C07D307/52;C07F5/02;C07F19/00 |
主分类号 |
C07F9/50 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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