发明名称 1,2-BIS(DIALKYLPHOSPHINO)-4,5-(METHYLENEDIOXY)BENZENE DERIVATIVE, METHOD FOR MANUFACTURING SAME, METAL COMPLEX HAVING THIS 1,2-BIS(DIALKYLPHOSPHINO)-4,5-(METHYLENEDIOXY)BENZENE DERIVATIVE AS A LIGAND, AND ASYMMETRIC HYDROGENATION METHOD
摘要 <p>Provided are a novel 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative that forms a metal complex having particularly high asymmetry induction capacity and catalytic activity on ß-dehydroamino acids, a method for manufacturing the same, a metal complex having this 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative as a ligand, and an asymmetric hydrogenation method using this metal complex. A 1,2-bis(dialkylphosphino)-4,5-(methylenedioxy)benzene derivative represented by general formula (1). (In the formula, R1 and R2 represent an alkyl group having 1-10 carbon atoms, and R1 and R2 have different numbers of carbon atoms.)</p>
申请公布号 WO2012176830(A1) 申请公布日期 2012.12.27
申请号 WO2012JP65831 申请日期 2012.06.21
申请人 NIPPON CHEMICAL INDUSTRIAL CO., LTD.;ZHANG ZHENFENG;IMAMOTO TSUNEO;TAMURA KEN 发明人 ZHANG ZHENFENG;IMAMOTO TSUNEO;TAMURA KEN
分类号 C07F9/50;C07B53/00;C07C231/18;C07C233/45;C07D307/52;C07F5/02;C07F19/00 主分类号 C07F9/50
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