发明名称 Synthesis of Caprolactam From Lysine
摘要 In various embodiments, the present invention can involve a method of synthesizing α-amino-&egr;-caprolactam. The method can comprise heating a salt of L-lysine in a solvent comprising an alcohol. In other embodiments, the present invention can involve methods for synthesizing &egr;-caprolactam. The methods can comprise heating a salt of L-lysine in a solvent comprising an alcohol and deaminating the reaction product. In various embodiments, the invention can include methods of converting biomass into nylon 6. The methods can comprise heating L-lysine in a solvent comprising an alcohol to produce α-amino-&egr;caprolactam, deaminating to produce &egr;-caprolactam and polymerizing into nylon 6, wherein the L-lysine is derived from the biomass. In other embodiments, the present invention can include methods of making nylon 6. The methods can comprise synthesizing &egr;-caprolactam and then polymerizing, wherein the &egr;-caprolactam is derived from L-lysine.
申请公布号 US2012142886(A1) 申请公布日期 2012.06.07
申请号 US201113175450 申请日期 2011.07.01
申请人 FROST JOHN W.;BOARD OF TRUSTEES OF MICHIGAN STATE UNIVERSITY 发明人 FROST JOHN W.
分类号 C08G69/16;C07D201/08;C07D223/10;C07D223/12 主分类号 C08G69/16
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