摘要 |
Calcium carbonate with high brightness is prepared by treating calcium carbonate and/or the milk of lime used for its preparation by reacting milk of lime with carbon dioxide and/or at least one of the calcium-containing preliminary products used for the preparation of the milk of lime before, during and/or after this reaction with a bleaching agent which comprises at least one compound of the formula (I): <?in-line-formulae description="In-line Formulae" end="lead"?>A[(CR<SUP>1</SUP>R<SUP>2</SUP>)SO<SUB>p</SUB>M<SUB>(1/q)</SUB>]<SUB>r</SUB> (I)<?in-line-formulae description="In-line Formulae" end="tail"?> where the variables have the following meanings: <tables id="TABLE-US-00001" num="00001"> <table frame="none" colsep="0" rowsep="0"> <tgroup align="left" colsep="0" rowsep="0" cols="2"> <colspec colname="1" colwidth="63pt" align="left"/> <colspec colname="2" colwidth="154pt" align="left"/> <THEAD> <ROW> <entry namest="1" nameend="2" align="center" rowsep="1"/> </ROW> </THEAD> <TBODY VALIGN="TOP"> <ROW> <ENTRY>A</ENTRY> <ENTRY>is NR<SUP>3</SUP>R<SUP>4</SUP>, NR<SUP>3</SUP>, N or OH;</ENTRY> </ROW> <ROW> <ENTRY>R<SUP>1</SUP>, R<SUP>2</SUP>, R<SUP>3</SUP>, R<SUP>4</SUP></ENTRY> <ENTRY>independently of one another, are hydrogen or</ENTRY> </ROW> <ROW> <ENTRY/> <ENTRY>an organic radical;</ENTRY> </ROW> <ROW> <ENTRY>M</ENTRY> <ENTRY>is ammonium or metal</ENTRY> </ROW> <ROW> <ENTRY>p</ENTRY> <ENTRY>is 2 or 3;</ENTRY> </ROW> <ROW> <ENTRY>q</ENTRY> <ENTRY>is the valency of M; and</ENTRY> </ROW> <ROW> <ENTRY>r</ENTRY> <ENTRY>is 1 when A = OH or NR<SUP>3</SUP>R<SUP>4</SUP>, is 2 when A = NR<SUP>3</SUP></ENTRY> </ROW> <ROW> <ENTRY/> <ENTRY>and is 3 when A = N;</ENTRY> </ROW> <ROW> <entry namest="1" nameend="2" align="center" rowsep="1"/> </ROW> </TBODY> </TGROUP> </TABLE> </TABLES> and where variables, if a mixture of compounds is used and/or r=2 or 3, are chosen independently of one another for each individual compound and/or for each [(CR<SUP>1</SUP>R<SUP>2</SUP>)SO<SUB>p</SUB>M<SUB>(1/q)</SUB>] group.
|