Process for preparing styrene by dehydrogenation of ethylbenzene and reaction system which can be used for the process

摘要

Process for the catalytic dehydrogenation of ethylbenzene in which a feedstock containing ethylbenzene and steam is supplied into the inlet of a tubular reactor containing a dehydrogehation catalyst. Within the reactor, the feedstock flows through at least a portion of the reactor along a spiral flow path extending longitudinally of the reactor. The resulting styrene product is then recovered from a downstream or outlet section of the reactor. The spiral flow path through which the feedstock is passed is located at least adjacent the inlet side of the reactor and at least a portion of the spiral flow path contains a particulate dehydrogenation catalyst. The spiral flow path may extend throughout a major portion of the elongated tubular reactor and may contain a particulate dehydrogenation catalyst in a substantial portion there.