发明名称 Crystallization enhancement of polyolefins
摘要 Polymer compositions having a first and second portion selected from polypropylenes, polyethylenes, propylene-ethylene copolymers and mixtures thereof having enhanced crystallization properties and a method for producing the same are disclosed. Antioxidant is mixed with the first portion, 0.01 to 1.25 wt %, of the composition which is then irradiated to a dosage of 5-30 Mrads of ionizing radiation in air to induce cross linking. The irradiated first portion is then blended with the non-irradiated second portion. The cross-linked polymer is believed to provide nucleation sites for the initiation of crystallization, thereby enhancing crystallization of the polymer as evidenced by elevated DSC freeze points. Crystallization of the polyolefin is enhanced without any detrimental effects on hexane or xylene extractability of the polymer and without degrading the composition to any appreciable extent.
申请公布号 US5266607(A) 申请公布日期 1993.11.30
申请号 US19910714602 申请日期 1991.06.13
申请人 REXENE PRODUCTS COMPANY 发明人 LUCAS, BENNIE M.;KRISHNAMURTHY, V.
分类号 C08J3/22;C08J3/28;C08L23/04;C08L23/06;C08L23/10;C08L23/12;C08L23/14;(IPC1-7):C08J3/28;C08K5/13;C08L23/30 主分类号 C08J3/22
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