发明名称 Process for the preparation of di-secondary alcohols and of glycidyl ethers thereof.
摘要 The present invention relates to the preparation of di-secondary alcohols comprising the reaction of an alcohol and a diglycidyl ether of a dihydric phenol in the presence of a catalyst of the formula (IV): MX (IV) wherein M is a metal from Groups IB to VIIIB or a metal or metalloid from Groups IIA to VA of the Periodic Chart of Elements or an ammonium ion and X is an anion selected from the group consisting of BF4<->, PF6<->, AsF6<->, SbF6<->, AlF4<->, TiF6<2><->, SiF6<2><-> and ZrF6<2><-> to produce the di-secondary alcohol, which can then be subjected to glycidylation to produce a glycidyl ether which are characterized by low viscosity, high purity and by low easily hydrolyzable chlorine content.
申请公布号 EP0528763(A2) 申请公布日期 1993.02.24
申请号 EP19920810605 申请日期 1992.08.07
申请人 CIBA-GEIGY AG 发明人 CHENG, CHI-WEN FRANK
分类号 B01J27/122;B01J27/128;B01J27/135;B01J27/138;B01J27/18;B01J27/24;C07B61/00;C07C41/03;C07C43/23;C07D301/27;C07D301/28;C07D303/18;C07D303/24;C08G59/00 主分类号 B01J27/122
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