| 摘要 |
PURPOSE:To obtain an amide by subjecting an oxime to rearrangement in the liquid phase in the presence of a compound such as an N,N-dialkylamide and phosphorus pentoxide. CONSTITUTION:An oxime is subjected to rearrangement in the liquid phase in the presence of at least one compound selected from N,N-dialkylamides, N-alkyl cyclic amides and dialkyl sulfoxides and phosphorus pentoxide. The aforementioned method is preferably applicable to rearrangement of a ketone oxime into an amide. The above-mentioned method is preferably applicable to cyclohexanone oxime, cyclopentane oxime, etc., as the oxime. |
