发明名称 PRODUCTION OF 4-METHYL-1-PENTENE
摘要 PURPOSE:To obtain the titled substance, by dimerizing propylene in the presence of a catalyst prepared by supporting an alkali metal on an anhydrous potassium carbonate carrier and by adding an alcohol, phenol, amine, ether or ketone having a specific number of carbons to the reaction system. CONSTITUTION:In obtaining the titled substance by dimerizing propylene, the reaction is carried out at 100-200 deg.C under 30-200kg/cm<2> in the presence of a catalyst prepared by supporting 1-5wt.% alkali metal (preferably Na or K) on an anhydrous potassium carbonate carrier by adding one or more compounds selected from 1-10C alcohols, 6-10C phenols, 3-30C amines, 2-20C ethers and 3-20C ketones (preferably one or more selected from aliphatic alcohol, aliphatic tertiary amine and alicyclic amine) to give the aimed substance while suppressing formation of 4-methyl-2-pentene as a by-product. The reaction may be carried out by batch system or flow system.
申请公布号 JPS63253037(A) 申请公布日期 1988.10.20
申请号 JP19870088067 申请日期 1987.04.09
申请人 SUMITOMO CHEM CO LTD 发明人 HIBI TAKAO;TOO YASUHIKO
分类号 B01J27/232;B01J31/26;C07B61/00;C07C1/00;C07C2/24;C07C2/26;C07C2/62;C07C11/113;C07C67/00 主分类号 B01J27/232
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