Rubber mixtures giving reversion-free vulcanizates and process of vulcanization

摘要

Mouldable and vulcanisable rubber mixtures are made containing a rubber (A) which still contains double bonds and which is cross-linkable by means of sulphur and a vulcanization accelerator or a mixture of rubber (A) with a different rubber (B), 0.2 to 10 parts of sulphur, 0.2 to 10 parts of a vulcanization accelerator and 1.0 to 10 parts of a bis-(alkoxysilylalkyl)polysulfide. There can also be present a silicate filler and/or a carbon black filler of rubber. The rubber mixtures have the silane, vulcanization accelerator and sulphur, calculated as S8 present in a molar ratio which causes the rubber mixture to have a reversion R=O (+/-5%) resulting from the cross-linking isotherm at the vulcanization temperature where the reversion R is calculated according to Formula II <IMAGE> in which Dmax is the maximum vulcameter moment of rotation Dmin is the minimum vulcameter moment of rotation D(max+60 min) is the vulcameter moment of rotation measured 60 minutes after the appearance of the maximum moment of rotation. There is also disclosed the process of vulcanizing the above-mentioned rubber mixtures or moulding compositions and forming vehicle tires using the rubber mixtures.