发明名称 PREPARATION OF CYCLOPROPANE CARBOXYLIC ACID ESTERS
摘要 3-(Halogenovinyl- or propenyl-)-2,2-dimethyl cyclopropane-1-carboxylic acid esters, which are precursors of, or may themselves be, pyrethroid insecticides, are prepared by the reaction of certain halogenopentadienes with an alkyl diazoacetate in the presence of a catalyst which is a transition metal complex of certain chiral Schiff bases, which catalysts tend to increase the yield of preferred cis IR isomer relative to the other possible isomers.
申请公布号 AU5858680(A) 申请公布日期 1981.01.15
申请号 AU19800058586 申请日期 1980.05.20
申请人 IMPERIAL CHEMICAL INDUSTRIES LTD. 发明人 D. A. LAIDLER;D. J. MILNER
分类号 C07C69/747;A01N53/00;A01N53/08;B01J31/00;B01J31/18;B01J31/28;C07B61/00;C07C67/00;C07C67/347;C07C69/743;C07C253/00;C07C255/39;C07D213/53;C07F1/00;C07H15/18;C07H15/26;C07H23/00 主分类号 C07C69/747
代理机构 代理人
主权项
地址