Process for the preparation of a composition comprising heterophasic propylene co-polymer and talc

摘要

The invention relates to a Process for the preparation of a composition comprising a heterophasic propylene copolymer and talc, wherein the heterophasic propylene copolymer consists of (a) a propylene-based matrix, wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene-α-olefin copolymer consisting of at least 70% by mass of propylene and up to 30% by mass of α-olefin, based on the total mass of the propylene-based matrix, wherein the propylene-based matrix is present in an amount of 60 to 95 wt % based on the total heterophasic propylene copolymer and (b) a dispersed ethylene-α-olefin copolymer, wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 40 to 5 wt % based on the total heterophasic propylene copolymer and wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %, wherein the composition has a desired melt flow index in the range of 1 to 200 dg/min as measured according to ISO1133 (2.16 kg/230° C.), wherein at least part of the talc is surface-modified and wherein the amount of talc in the composition is from about 0.5 to at most 5 wt % based on the heterophasic propylene copolymer, comprising the step of (a) melt-mixing the heterophasic propylene copolymer with the talc and a peroxide, wherein the amount of peroxide is chosen such that a composition comprising a heterophasic propylene copolymer and talc having the desired melt flow index is obtained.

主权项

1. A process for the preparation of a composition comprising a heterophasic propylene copolymer and talc, wherein the heterophasic propylene copolymer consists of
(a) a propylene-based matrix, wherein the propylene-based matrix consists of a propylene homopolymer and/or a propylene-α-olefin copolymer consisting of at least 70% by mass of propylene and up to 30% by mass of ethylene, based on the total mass of the propylene-based matrix, and wherein the propylene-based matrix is present in an amount of 60 to 95 wt % based on the total heterophasic propylene copolymer and, (b) a dispersed ethylene-α-olefin copolymer, wherein the dispersed ethylene-α-olefin copolymer is present in an amount of 40 to 5 wt % based on the total heterophasic propylene copolymer and wherein the sum of the total amount of propylene-based matrix and total amount of the dispersed ethylene-α-olefin copolymer in the heterophasic propylene copolymer is 100 wt %, wherein the composition has a desired melt flow index in the range of 1 to 200 dg/min as measured according to ISO1133 (2.16 kg/230° C.),wherein at least 80 wt % of the talc is surface-modified with a polar substance comprising ethylene-bis-stearamide and wherein the amount of talc in the composition is from about 0.5 to at most 5 wt % based on the heterophasic propylene copolymer,
comprising the step of
(a) melt-mixing the heterophasic propylene copolymer with the talc and a peroxide,wherein the amount of peroxide is chosen such that a composition comprising a heterophasic propylene copolymer and talc having the desired melt flow index is obtained,wherein the α-olefin in the propylene-α-olefin copolymer is selected from the group of α-olefins having 2 or 4-10 carbon atoms,wherein the amount of ethylene in the ethylene-α-olefin copolymer is in the range of 20-65 wt % based on the ethylene-α-olefin copolymer andwherein the α-olefin in the ethylene-α-olefin copolymer is chosen from the group of α-olefins having 3 to 8 carbon atoms and any mixtures thereof.