| 主权项 |
1. A composition for forming a gate insulating film, comprising:
an insulating material; and a migration inhibitor selected from the group consisting of a compound represented by any of Formulae (1) to (8), a polymer compound (X) containing a repeating unit represented by Formula (A), and a polymer compound (Y) containing a repeating unit represented by Formula (B) and a repeating unit represented by Formula (C),
P—(CR1═Y)n-Q Formula (1) (in Formula (1), each of P and Q independently represents OH, NR2R3, or CHR4R5; each of R2 and R3 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom; each of R4 and R5 independently represents a hydrogen atom or a substituent; Y represents CR6 or a nitrogen atom; each of R1 and R6 independently represents a hydrogen atom or a substituent; at least two out of the groups represented by R1, R2, R3, R4, R5, or R6 may form a ring by being bonded to each other; n represents an integer of 0 to 5; when n is 0, P and Q do not represent CHR4R5 at the same time and do not represent OH at the same time; when n represents a number of equal to or greater than 2, a plurality of atomic groups represented by (CR1═Y) may be the same as or different from each other; and at least one of the groups represented by R1 to R6 contains a fluorine atom),
R7—C(═O)—H Formula (2) (in Formula (2), R7 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups; the group represented by R7 may contain a hydroxy group or a group represented by —COO—; and in the group represented by R7, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom), (in Formula (3), each of R8, R9, and R10 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups, and in at least one of the groups represented by R8 to R10, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom), (in Formula (4), each of R11 and R12 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups; in at least one of the groups represented by R11 and R12, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom; and R11 and R12 may form a ring by being bonded to each other),
Z—SH Formula (5) (in Formula (5), Z represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups; the group represented by Z may contain a substituent; and in the group represented by Z, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom), (in Formula (6), each of X61, X62, and X63 independently represents —NH—, —N═, ═N—, —CRx═, ═CRx—, or —S—; Rx represents a hydrogen atom, —NH2, or a linear or branched alkyl group having 1 to 15 carbon atoms; in the alkyl group, one carbon atom or two or more carbon atoms which are not adjacent to each other may be substituted with —O—, —S—, —NR0, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CR0═CR00—, or —C≡C—; one or more hydrogen atoms in the alkyl group may be substituted with a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or —CN; each of R0 and R00 independently represents a hydrogen atom or a carbyl or hydrocarbyl group which may have a substituent and one or more heteroatoms; and at least one of X61, X62, and X63 is not —CRx═ or ═CRx—, each of R61 and R62 independently represents a fluorine atom, a chlorine atom, -Sp-P, a linear or branched alkyl group having 1 to 15 carbon atoms, or an aryl group, a heteroaryl group, an aryloxy group, a heteroaryloxy group, an arylcarbonyl group, a heteroarylcarbonyl group, an arylcarbonyloxy group, a heteroarylcarbonyloxy group, an aryloxycarbonyl group, or a heteroaryloxycarbonyl group which has 2 to 30 carbon atoms and may have a substituent; in the alkyl group, one carbon atom or two or more carbon atoms which are not adjacent to each other may be substituted with —O—, —S—, —NR0, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CR0═CR00—, or —C≡C—; one or more hydrogen atoms in the alkyl group may be substituted with a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or —CN; each of R0 and R00 independently represents a hydrogen atom or a carbyl or hydrocarbyl group which may have a substituent and one or more heteroatoms; Sp represents a single bond or a divalent organic group; P represents a polymerizable group or a cross-linking group; R61 and R62 may form an aromatic ring or an aromatic heterocyclic ring having 5 to 7 ring atoms by being bonded to each other; the aromatic ring and the aromatic heterocyclic ring may have 1 to 6 substituents; and in at least one of the groups represented by R61, R62, X61, X67, and X63, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom), (in Formula (7), each of R71 and R72 independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups, and in at least one of the groups represented by R71 and R72, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom),
Z1-S—S—Z2 Formula (8) (in Formula (8), each of Z1 and Z2 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups; at least one of Z1 and Z2 may contain a substituent; and in at least one of Z1 and Z2, a portion of hydrogen atoms or the entirety of hydrogen atoms are substituted with a fluorine atom), (in Formula (A), RA represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms that may have a substituent; LA represents a single bond or a divalent organic group; A represents a monovalent group, which is formed as a result of removing one hydrogen atom (here, a hydrogen atom of a hydroxyl group is excluded) from the compounds represented by Formulae (1) to (8), or a monovalent group formed as a result of removing one fluorine atom from a compound which belongs to the compounds represented by Formulae (1) to (8) and has 2 or more fluorine atoms in a molecule), (in Formula (B), RB represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms that may have a substituent; LB represents a single bond or a divalent organic group; and B represents a monovalent group, which is formed as a result of removing one hydrogen atom (here, a hydrogen atom of a hydroxyl group is excluded) from compounds represented by the following Formulae (Y-1) to (Y-8), or a group represented by the following Formula (25), in Formula (C), RC represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms that may have a substituent; LC represents a single bond or a divalent organic group; X represents a hydrogen atom, a fluorine atom, or a trifluoromethyl group; Rf represents a fluoroalkyl group having 20 or less carbon atoms that may have an ethereal oxygen atom, in which at least one hydrogen atom is substituted with a fluorine atom, or a fluorine atom),
P—(CR1═Y)n-Q Formula (Y-1) (in Formula (Y-1), each of P and Q independently represents OH, NR2R3, or CHR4R5; each of R2 and R3 independently represents a hydrogen atom or a group which can be substituted with a nitrogen atom; each of R4 and R5 independently represents a hydrogen atom or a substituent; Y represents CR6 or a nitrogen atom; each of R1 and R6 independently represents a hydrogen atom or a substituent; at least two out of the groups represented by R1, R2, R3, R4, R5, and R6 may form a ring by being bonded to each other; n represents an integer of 0 to 5; when n is 0, P and Q do not represent CHR4R5 at the same time and do not represent OH at the same time; and when n represents a number of equal to or greater than 2, a plurality of atomic groups represented by (CR1═Y) may be the same as or different from each other),
R7—C(═O)—H Formula (Y-2) (in Formula (Y-2), R7 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups, and the group represented by R7 may contain a hydroxy group or a group represented by —COO—), (in Formula (Y-3), each of R8, R9, and R10 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups), (in Formula (Y-4), each of R11 and R12 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups, and R11 and R12 may form a ring by being bonded to each other),
Z—SH Formula (Y-5) (in Formula (Y-5), Z represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups, and the group represented by Z may contain a substituent), (in Formula (Y-6), each of X61, X62, and X63 independently represents —NH—, —N═, ═N—, —CRx═, ═CRx—, or —S—; Rx represents a hydrogen atom, —NH2, or a linear or branched alkyl group having 1 to 15 carbon atoms; in the alkyl group, one carbon atom or two or more carbon atoms which are not adjacent to each other may be substituted with —O—, —S—, —NR0, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CR0═CR00—, or —C≡C—; one or more hydrogen atoms in the alkyl group may be substituted with a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or —CN; each of R0 and R00 independently represents a hydrogen atom or a carbyl or hydrocarbyl group which may have a substituent and one or more heteroatoms; and at least one of X61, X62, and X63 is not —CRx═ or ═CRx—, each of R61 and R62 independently represents a fluorine atom, a chlorine atom, -Sp-P, a linear or branched alkyl group having 1 to 15 carbon atoms, or an aryl group, a heteroaryl group, an aryloxy group, a heteroaryloxy group, an arylcarbonyl group, a heteroarylcarbonyl group, an arylcarbonyloxy group, a heteroarylcarbonyloxy group, an aryloxycarbonyl group, or a heteroaryloxycarbonyl group which has 2 to 30 carbon atoms and may have a substituent; in the alkyl group, one carbon atom or two or more carbon atoms which are not adjacent to each other may be substituted with —O—, —S—, —NR0, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —CR0═CR00—, or —C≡C—; one or more hydrogen atoms in the alkyl group may be substituted with a fluorine atom, a chlorine atom, a bromine atom, an iodine atom, or —CN; each of R0 and R00 independently represents a hydrogen atom or a carbyl or hydrocarbyl group which may have a substituent and one or more heteroatoms; Sp represents a single bond or a divalent organic group; P represents a polymerizable group or a cross-linking group; R61 and R62 may form an aromatic ring or an aromatic heterocyclic ring having 5 to 7 ring atoms by being bonded to each other; and the aromatic ring and the aromatic heterocyclic ring may have 1 to 6 substituents), (in Formula (Y-7), each of R71 and R72 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups),
Z1-S—S—Z2 Formula (Y-8) (in Formula (Y-8), each of Z1 and Z2 independently represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heterocyclic group, or a group which is obtained by combining these groups, and at least one of Z1 and Z2 may contain a substituent), (in Formula (25), each of R251, R252, R253, and R254 independently represents a hydrogen atom or a substituent, and * represents a binding position). |
