发明名称 SELECTIVE HYDROGENATION OF ALDEHYDES WITH RU/BIDENTATE LIGANDS COMPLEXES
摘要 The present invention relates to processes for the reduction by hydrogenation, using molecular H2, of a C5-C20 substrate containing one or two aldehydes functional groups into the corresponding alcohols or diol, characterized in that said process is carried out in the presence of—at least one catalyst or pre-catalyst in the form of a ruthenium complex having a coordination sphere of the N1P3O2, wherein the coordinating atom N and one coordinating atom P are provided by a first bidentate ligand, and the two other coordinating atoms P2 are provided by a second bidentate ligand and the coordinating atoms O2 are provided by two non-linear carboxylate ligands; and—optionally of an acidic additive.
申请公布号 EP2970067(A1) 申请公布日期 2016.01.20
申请号 EP20140711936 申请日期 2014.03.06
申请人 FIRMENICH SA 发明人 DUPAU, PHILIPPE;BONOMO, LUCIA;KERMORVAN, LAURENT
分类号 C07C29/157;C07F15/00 主分类号 C07C29/157
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