发明名称 |
METHOD OF OBTAINING POLYHYDRO[60]FULLERENES |
摘要 |
FIELD: chemistry. ^ SUBSTANCE: invention concerns method of obtaining polyhydro[60]fullerenes of formula (1): , involving fullerene C60 interaction with diisobutylaluminum chloride (i-Bu2AlCl) in the presence of zirconocene dichloride catalyst (Cp2ZrCl2) at molar ratio of C60:i-Bu2AlCl:Cp2ZrCl2=1:(55-65):(0.15-0.25), preferably 1:60:0.20, in argon atmosphere in the absence of light at room temperature of 60-100°C and atmospheric pressure in toluene medium for 1-5 hours, with further hydrolysis of reaction mass. The method allows obtaining total 77-91% output of polyhydro[60]fullerene after reaction mass hydrolysis. ^ EFFECT: improved method. ^ 1 tbl, 7 ex
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申请公布号 |
RU2348601(C1) |
申请公布日期 |
2009.03.10 |
申请号 |
RU20070128211 |
申请日期 |
2007.07.23 |
申请人 |
INSTITUT NEFTEKHIMII I KATALIZA RAN |
发明人 |
DZHEMILEV USEIN MEMETOVICH;TUKTAROV AJRAT RAMILEVICH;AKHMETOV ARSLAN RIFKHATOVICH;D'JAKONOV VLADIMIR ANATOL'EVICH;IBRAGIMOV ASKHAT GABDRAKHMANOVICH |
分类号 |
C07C13/64;B01J21/02;B01J21/06;B01J31/14;C07C5/02 |
主分类号 |
C07C13/64 |
代理机构 |
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