发明名称 METHOD FOR PRODUCING FLUORINE-CONTAINING ALKYLETHYL HALIDE AND FLUORINE-CONTAINING ALKANE
摘要 PROBLEM TO BE SOLVED: To provide a method for efficiently producing a fluorine-containing alkylethyl halide and a fluorine-containing alkane and to provide a method for efficiently producing a fluorine-containing ester. SOLUTION: The method for production is characterized as follows. A fluorine-containing alkene represented by general formula (I) R<SB>f</SB><SP>1</SP>-CH=CH<SB>2</SB>(I) (wherein, R<SB>f</SB><SP>1</SP>denotes a 1-20C perfluoroalkyl group or the like) is reacted with a fluorine-containing alkyl halide represented by general formula (II): Y-R<SB>f</SB><SP>2</SP>-X<SP>1</SP>(wherein, R<SB>f</SB><SP>2</SP>denotes a 1-20C perfluoroalkylene group or the like; Y denotes an H or an F; and X<SP>1</SP>denotes a Cl, a Br or an I) and a hydrogen donor in the presence or absence of a catalyst. The method is to simultaneously produce the fluorine-containing alkylethyl halide represented by general formula (III): R<SB>f</SB><SP>1</SP>-CH<SB>2</SB>CH<SB>2</SB>-X<SP>1</SP>[wherein, R<SB>f</SB><SP>1</SP>and X<SP>1</SP>are each as defined in general formula (I) and general formula (II)] and the fluorine-containing alkane represented by general formula (IV): Y-R<SB>f</SB><SP>2</SP>-H [wherein, R<SB>f</SB><SP>2</SP>and Y are each as defined in general formula (II)]. COPYRIGHT: (C)2004,JPO&NCIPI
申请公布号 JP2004256406(A) 申请公布日期 2004.09.16
申请号 JP20030046937 申请日期 2003.02.25
申请人 DAIKIN IND LTD 发明人 HASEGAWA TOMOKUNI;KATSUBE TOSHIYUKI;MIKI ATSUSHI
分类号 C07C17/087;C07B61/00;C07C17/23;C07C19/08;C07C19/16;C07C67/10;C07C69/653;C08K5/02;C08L27/12;(IPC1-7):C07C17/087 主分类号 C07C17/087
代理机构 代理人
主权项
地址