发明名称 Process for producing 3,3-dimethyl-2-formylcyclopropane-carboxylic acid ester
摘要 There is provided a process for producing 3,3-dimethyl-2-formylcyclopropanecarboxylic ester of formula (1):wherein R represents an alkyl group, a cycloalkyl group or an optionally substituted aralkyl group,which comprises reacting chrysanthemic acid ester of formula (2):wherein R represents the same meaning as that described above, with hydrogen peroxide in the presence of at least one catalyst selected from tungstic oxide, tungstic acid, tugstate, alkylrhenium trioxide, molybdic oxide, molybdate, a heteropoly acid comprising a hetero atom selected from a phosphorus, boron or silicone atom and a poly atom selected from tungsten or molybdenum and a salt of said heteropoly acid.
申请公布号 US6489505(B2) 申请公布日期 2002.12.03
申请号 US20010769290 申请日期 2001.01.26
申请人 SUMITOMO CHEMICAL COMPANY, LIMITED 发明人 HAGIYA KOJI;KOMOTO ICHIRO;KURIHARA AKIO
分类号 C07C69/74;C07C67/333;(IPC1-7):C07C69/66;C07C69/72 主分类号 C07C69/74
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