发明名称 COMPOUND HAVING VINYLIMIDAZOLIUM BASE AND PRODUCTION THEREOF
摘要 NEW MATERIAL:A compound expressed by formula I [R1 is H, 1-17C alkyl or 6-8C aryl; R2 and R3 are H or 1-3C alkyl; X<-> is halide ion, hydroxide ion, 1/2(sulfate ion), nitrate ion or RCOO<-> (R is 1-3C alkyl)]. EXAMPLE:A compound expressed by formula II. USE:A crosslinking agent having strong basicity (imidazolium base), readily copolymerizable and capable of giving a polymer by radical polymerization by itself or with another monomer and readily producing ion exchange resins (membranes) having high ion exchange capacity particularly when using a vinyl monomer having strong basicity as another monomer. PREPARATION:A 1-vinylimidazole expressed by formula II is reacted with a xylylene dihalide, preferably p-isomer in a solvent, e.g. methanol, etc., at 10-120 deg.C for 1-30hr and, as necessary, halogen ions are converted into X<-> to afford the aimed compound expressed by formula I.
申请公布号 JPS62116564(A) 申请公布日期 1987.05.28
申请号 JP19850258147 申请日期 1985.11.18
申请人 MITSUBISHI PETROCHEM CO LTD 发明人 TODA HIDEO;GODA JUNKO;KIHARA KUNIO
分类号 C07D233/58;B01D15/04;C08F26/00;C08F26/06 主分类号 C07D233/58
代理机构 代理人
主权项
地址