Metal coordination complexes of heteropolyacids as catalysts for alcohol conversion

摘要

A new catalyst system for the conversion of short-chain aliphatic alcohols to hydrocarbons having the formula [MLq]bm+[N]dn+[Xp+YaZ(12-a)O40]-(8-p) wherein: [ML] is an organometallic compound where M is at least one metal selected from Group IIIA, IVA, VA, IB, IIB, IVB, VB, VIA, Fe, Co, and Ni; and L is an organic ligand, N is a positively charged species including a positively charged organic ligand, X is at least one element selected from P, Si, As, Ti, Zr, B, Co, Cu or Sn, Y and Z are independently selected from W, Mo, or V, m+n=[-p q=1-6 O