发明名称 Supported Bis Phenolate Transition Metals Complexes, Production and Use Thereof
摘要 A catalyst system including the reaction product of a fluorided support, an activator, and at least a first transition metal catalyst compound; methods of making such catalyst systems, polymerization processes using such catalyst systems, and polymers made therefrom.
申请公布号 US2017096510(A1) 申请公布日期 2017.04.06
申请号 US201615242357 申请日期 2016.08.19
申请人 ExxonMobil Chemical Patents Inc. 发明人 Ye Xuan;Atienza Crisita Carmen H.;Holtcamp Matthew W.;Sanders David F.;Day Gregory S.;Titone Michelle E.;Cano David A.;Bedoya Matthew S.
分类号 C08F210/16 主分类号 C08F210/16
代理机构 代理人
主权项 1. A catalyst system comprising the reaction product of a fluorided support, an activator and a catalyst compound of Formula I: wherein: M is a Group 4 transition metal; X and X2 are, independently, a univalent C1 to C20 hydrocarbyl radical, a C1 to C20 substituted hydrocarbyl radical, a heteroatom or a heteroatom-containing group, or X1 and X2 join together to form a C4 to C62 cyclic or polycyclic ring structure; each R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 is, independently, a hydrogen, a C1 to C40 hydrocarbyl radical, a C1-C40 substituted hydrocarbyl radical, a heteroatom or a heteroatom-containing group, or two or more of R1 to R10 may independently join together to form a C4 to C62 cyclic or polycyclic ring structure, or a combination thereof; Q is a neutral donor group; J is a C7 to C60 fused polycyclic group, which optionally comprises up to 20 atoms from Groups 15 and 16, where at least one ring is aromatic and where at least one ring, which may or may not be aromatic, has at least five members; G is as defined for J or may be hydrogen, a C1-C60 hydrocarbyl radical, a C1-C60 substituted hydrocarbyl radical, a heteroatom or a heteroatom-containing group, or may independently form a C4 to C60 cyclic or polycyclic ring structure with R6, R7, or R8 or a combination thereof; and Y is a divalent C1 to C20 hydrocarbyl or divalent C1 to C20 substituted hydrocarbyl.
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