发明名称 PRODUCTION OF ORGANOSILICON COMPOUND HAVING ALPHA, BETA- UNSATURATED CARBOXYL GROUP, COMPOSITION CONTAINING THE COMPOUND, AND OPTICALLY ANISOTROPIC LAYER
摘要 PROBLEM TO BE SOLVED: To efficiently produce an organosilicon compound capable of being cross-linked and useful for formation or the like of an optically anisotropic layer in high purity and high yield by reacting each specific organosilicon compound with olefinic unsaturated compound, and removing a prescribed group. SOLUTION: (H) An organosilicon compound having hydrogen atom directly bonded to the silicon is reacted with (U) an olefinic unsaturated compound represented by formula I (Ωis a monovalent organic group having a terminal double bond or triple bond; R is H or methyl; and Z is Cl, I, Br or 4- methyltoluenesulfonyl), and having a double bond or a triple bond in the presence of a metal or a compound of the platinum group as a catalyst to provide (E) an organosilicon compound represented by formula II (A is a divalent organic group), and H-Z is removed from the obtained organosilicon compound E to provide (P) the objective organosilicon compound represented by formula III and having anα,β-unsaturated carboxylic acid group.
申请公布号 JP2000229985(A) 申请公布日期 2000.08.22
申请号 JP20000016143 申请日期 2000.01.25
申请人 CONSORTIUM ELEKTROCHEM IND GMBH 发明人 HANELT ECKHARD;SANDMEYER FRANK;HAEBERLE NORMAN;SCHINDLER WOLFRAM
分类号 B01J27/10;C07B61/00;C07F7/02;C07F7/08;C07F7/14;C08G77/04;C09K19/40;(IPC1-7):C07F7/08 主分类号 B01J27/10
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