发明名称 Electrically conducting polymers doped with heteropolyanions, process for their manufacture and their use in chemical and electrochemical catalysis.
摘要 An electronically conductive polymer doped with anions of a heteropolyacid of formula: Hn(XMyVy',Oz> in which n, y, y' and z are such that 2</=n</=6, 6</=y</=18, 0</=y'</=12, 24</=z</=70 and 6</=y+y'</=18, X is an element such as P or Si, and M is Mo or W. These polymers can be prepared by chemical or electrochemical oxidation from a solution containing the heteropolyacid and the monomer capable of forming an electronically conductive polymer by oxidation, for example pyrrole, thiophene, aniline, para- phenylenediamine, acetylene, benzene and their substituted derivatives. The doped electronically conductive polymer obtained can reduce the protons of a solution as shown by the curve (1) of enclosed Figure 2. <IMAGE>
申请公布号 EP0323351(A1) 申请公布日期 1989.07.05
申请号 EP19880403338 申请日期 1988.12.27
申请人 COMMISSARIAT A L'ENERGIE ATOMIQUE 发明人 BIDAN, GERARD;GENIES, EUGENE;LAPROWSKI, MIETTCZYSLAW
分类号 B01J31/34;B01J27/188;B01J27/19;B01J31/06;B01J35/00;C07B61/00;C08G61/12;C08K3/22;C08L65/02;C08L101/00;C25B11/00;H01B1/12;H01M4/60;H01M4/90 主分类号 B01J31/34
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