| 摘要 |
<p>Catalysts for the polymerization of alpha-olefins, comprising the product of the reaction between:
<UnorderedLists id="ula01" listStyle="none"><ListItem>a) a metallorganic Al compound;</ListItem><ListItem>b) an electron-donor compound reactive towards MgC1<Sub>2</Sub> but which results not to be completely complexed with Al-triethyl at the equivalent point of the potentiometric titration under standard conditions;</ListItem><ListItem>c) a solid comprising a halogenated Ti compound supported on an anhydrous Mg halide and at least one of the following activators:</ListItem><ListItem>1) an Al, Fe, Mn, Sb or Zn compound containing at least one metal-halogen bond;</ListItem><ListItem>2) a complex between an electron-donor compound and a Lewis acid chosen among the halides of the metals of Groups II-VIII of the Periodic System other than Ti;</ListItem><ListItem>3) a compound or composition, inert towards the Mg halide, having a dielectric constant at 20°C higher than 2; compounds 1), 2) and 3) being extractable from the solid for at least 30% by mols by treatment with toluene at 80°C for 2 hours, and the surface area of the solid after extraction being higher than 20 m<Sup>2</Sup>/g.</ListItem></UnorderedLists></p> |
