发明名称 PROCESS FOR PREPARING CYCLIC ACETALS WHICH CAN BE USED AS FUEL COMPONENTS
摘要 The present invention relates to a process for preparing cyclic acetals having general formula (I) wherein Y and Y', equal to or different from each other, are selected from H and a group OR, R being a linear or branched alkyl containing from 1 to 8 carbon atoms, comprising at least the following phases: (i) providing a reaction mixture comprising at least one vicinal diol having formula (II) Z-CH2-CHOH-CH2OH wherein Z is selected from H and a group OR', R' being a linear or branched alkyl containing from 1 to 8 carbon atoms, said mixture being substantially free of aldehydes having general formula RI-CHO, wherein RI is a linear or branched alkyl containing from 1 to 6 carbon atoms, possibly substituted by an alkoxide group OR111, wherein RIII is an alkyl containing from 1 to 4 carbon atoms; (ii) thermally treating said reaction mixture at a temperature within the range of 100°C - 300°C in the presence of at least one acid catalyst, obtaining said compound having formula (I). The acetals having formula (I) can be used as fuel components.
申请公布号 EP3129448(A1) 申请公布日期 2017.02.15
申请号 EP20150721852 申请日期 2015.04.03
申请人 Eni S.p.A. 发明人 ASSANELLI, Giulio;DE ANGELIS, Alberto Renato
分类号 C10L1/185;C07D317/26 主分类号 C10L1/185
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