发明名称 HIGH TEMPERATURE ISOMERIZATION OF (E)-1-CHLORO-3,3,3-TRIFLUOROPROPENE TO (Z)-1-CHLORO-3,3,3-TRIFLUOROPROPENE
摘要 Disclosed are processes for a high temperature isomerization reaction converting (E)-1-chloro-3,3,3-trifluoropropene to (Z)-1-chloro-3,3,3-trifluoropropene. In certain aspects of the invention, such a process includes contacting a feed stream with a heated surface, where the feed stream includes (E)-1-chloro-3,3,3-trifluoropropene or mixture of (E)-1-chloro-3,3,3-trifluoropropene with (Z)-1-chloro-3,3,3-trifluoropropene. The resulting product stream includes (Z)-1-chloro-3,3,3-trifluoropropene and (E)-1-chloro-3,3,3-trifluoropropene, where the ratio of (Z) isomer to (E) isomer in the product stream is higher than the ratio feed stream. The (E) and (Z) isomers in the product stream may be separated from one another.
申请公布号 EP2970047(A1) 申请公布日期 2016.01.20
申请号 EP20140770253 申请日期 2014.03.13
申请人 HONEYWELL INTERNATIONAL INC. 发明人 POKROVSKI, KONSTANTIN A.;MERKEL, DANIEL C.;TUNG, HSUEH S.
分类号 C07C5/22;C07B35/08;C07B63/00;C07C17/358 主分类号 C07C5/22
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