发明名称 |
PHOSPHONIUM BORATE COMPOUND AND METHOD OF USING THE SAME |
摘要 |
<p>The invention relates to a phosphonium borate compound represented by Formula (I) (hereinafter, the compound (I)). The invention has objects of providing (A) a novel process whereby the compound is produced safely on an industrial scale, by simple reaction operations and in a high yield; (B) a novel compound that is easily handled; and (C) novel use as catalyst.
€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒFormula (I) : (R 1 )(R 2 )(R 3 )PH·BAr 4 €ƒ€ƒ€ƒ€ƒ€ƒ(I)
wherein R 1 , R 2 , R 3 and Ar are as defined in the specification. The process (A) includes reacting a phosphine with a) HCl or b) H 2 SO 4 to produce a) a hydrochloride or b) a sulfate; and reacting the salt with a tetraarylborate compound. The compound (B) has for example a secondary or tertiary alkyl group as R 1 and is easily handled in air without special attention. The use (C) is characterized in that the compound (I) is used instead of an unstable phosphine compound of a transition metal complex catalyst for catalyzing C-C bond, C-N bond and C-O bond forming reactions and the compound produces an effect that is equal to that achieved by the transition metal complex catalyst.</p> |
申请公布号 |
EP1688424(B1) |
申请公布日期 |
2016.01.13 |
申请号 |
EP20040819465 |
申请日期 |
2004.11.26 |
申请人 |
HOKKO CHEMICAL INDUSTRY CO., LTD. |
发明人 |
MASAOKA, SHIN;IWAZAKI, HIDEYUKI |
分类号 |
C07F9/54;B01J31/02;C07C1/32;C07C29/32;C07C33/30;C07C33/48;C07C41/16;C07C45/68;C07C49/782;C07C49/796;C07C67/343;C07C69/612;C07C69/618;C07C209/10;C07C211/54;C07C213/08;C07C215/68;C07C227/08;C07C229/44;C07C253/30 |
主分类号 |
C07F9/54 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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