摘要 |
<p>A flexible organic thermoelectric conversion element which comprises an organic thermoelectric conversion layer that contains (a) carbon nanotubes, (b) a polymer compound and (c) a compound represented by formula (A), formula (B) or formula (C) and is provided on a flexible base in a pattern corresponding to the arrangement of a metal electrode that is provided on the flexible base, and an upper electrode that is provided on the organic thermoelectric conversion layer; a method for manufacturing this flexible organic thermoelectric conversion element; an article for thermoelectric power generation; and a power supply for sensors. R1-Y Formula (A) R1-Z1-C(=S)-Z2-R2 Formula (B) R1-Z3-Z3-R3 Formula (C) In formulae (A), (B) and (C), R1 represents an alkyl group, an alkenyl group, an aralkyl group or an aryl group; Y represents -SH, -SCN or -SiR4R5H; each of Z1 and Z2 independently represents a single bond, an oxygen atom, a sulfur atom or -NR6-; Z3 represents a sulfur atom, -(C=S)-S- or -NR7-(C=S)-S-; each of R2 and R3 independently represents an alkyl group, an alkenyl group, an aralkyl group or an aryl group; R2 may combine with R1 to form a ring; each of R4, R5, R6 and R7 independently represents a hydrogen atom, an alkyl group, an aralkyl group or an aryl group; and R7 may combine with R1 or R3 to form a ring.</p> |