发明名称 Method for manufacturing olefins
摘要 The present invention relates to a process for producing an olefin, including the step of subjecting an aliphatic primary alcohol having 12 to 24 carbon atoms to liquid phase dehydration reaction in the presence of a solid acid catalyst, wherein among a total acid content of the solid acid catalyst as measured by an ammonia temperature-programmed desorption (NH3-TPD) method, an acid content of the solid acid catalyst as calculated from an amount of ammonia desorbed at a temperature not higher than 300° C. in the method is 70% or larger of the total acid content.
申请公布号 US9000248(B2) 申请公布日期 2015.04.07
申请号 US201013504662 申请日期 2010.10.29
申请人 KAO Corporation 发明人 Takada Shingo
分类号 C07C1/20;B01J35/00;B01J21/04;B01J27/18;C07C1/24;C10G3/00 主分类号 C07C1/20
代理机构 Oblon, McClelland, Maier & Neustadt, L.L.P. 代理人 Oblon, McClelland, Maier & Neustadt, L.L.P.
主权项 1. A process for producing an olefin, comprising subjecting an aliphatic primary alcohol having 12 to 24 carbon atoms to liquid phase dehydration reaction in the presence of a solid acid catalyst, wherein among a total acid content of the solid acid catalyst as measured by an ammonia temperature-programmed desorption (NH3-TPD) method, an acid content of the solid acid catalyst as calculated from an amount of ammonia desorbed at a temperature not higher than 300° C. in the method is 70% or larger of the total acid content, wherein said liquid phase dehydration reaction is carried out at a temperature of from 160 to 290° C. and wherein the solid acid catalyst is alumina or aluminum phosphate.
地址 Tokyo JP