发明名称 |
Method for manufacturing olefins |
摘要 |
The present invention relates to a process for producing an olefin, including the step of subjecting an aliphatic primary alcohol having 12 to 24 carbon atoms to liquid phase dehydration reaction in the presence of a solid acid catalyst, wherein among a total acid content of the solid acid catalyst as measured by an ammonia temperature-programmed desorption (NH3-TPD) method, an acid content of the solid acid catalyst as calculated from an amount of ammonia desorbed at a temperature not higher than 300° C. in the method is 70% or larger of the total acid content. |
申请公布号 |
US9000248(B2) |
申请公布日期 |
2015.04.07 |
申请号 |
US201013504662 |
申请日期 |
2010.10.29 |
申请人 |
KAO Corporation |
发明人 |
Takada Shingo |
分类号 |
C07C1/20;B01J35/00;B01J21/04;B01J27/18;C07C1/24;C10G3/00 |
主分类号 |
C07C1/20 |
代理机构 |
Oblon, McClelland, Maier & Neustadt, L.L.P. |
代理人 |
Oblon, McClelland, Maier & Neustadt, L.L.P. |
主权项 |
1. A process for producing an olefin, comprising subjecting an aliphatic primary alcohol having 12 to 24 carbon atoms to liquid phase dehydration reaction in the presence of a solid acid catalyst,
wherein among a total acid content of the solid acid catalyst as measured by an ammonia temperature-programmed desorption (NH3-TPD) method, an acid content of the solid acid catalyst as calculated from an amount of ammonia desorbed at a temperature not higher than 300° C. in the method is 70% or larger of the total acid content, wherein said liquid phase dehydration reaction is carried out at a temperature of from 160 to 290° C. and wherein the solid acid catalyst is alumina or aluminum phosphate. |
地址 |
Tokyo JP |