| 摘要 |
A catalyst and a catalyst packing schedule are designed so that a relation between the raw material conversion rate at which the yield of the objective product becomes maximum and the raw material conversion rate at which a high and low correlation between maximum temperature of the catalyst layer present closest to a reaction gas inlet side Zin and maximum temperature of the catalyst layer present closest to a reaction gas outlet side Zout is reversed satisfies a specific condition of 0.5≦Cmax−Ccrs≦5, in which Cmax: a raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: a raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate is changed, a high and low correlation between Tin and Tout is reversed. |
| 主权项 |
1. A process for producing acrolein and acrylic acid or methacrolein and methacrylic acid by subjecting propylene or at least one kind selected from isobutylene and tertiary butanol to vapor-phase catalytic oxidation with a gas containing molecular oxygen using a fixed bed multitubular reactor, the process comprising:
A) providing a plurality of catalyst layers formed by division into N, where N represents an integer of 2 or more, in a raw material gas flow direction of reaction tubes and regarding the catalyst layer present closest to a reaction gas inlet side among the catalyst layers as Zin and the catalyst layer present closest to a reaction gas outlet side among the catalyst layers as Zout; and B) packing a catalyst so that activity of the catalyst packed in Zout becomes higher than activity of the catalyst packed in Zin to satisfy the following expression (1):
0.5≦Cmax−Ccrs≦5 expression (1) Cmax: the raw material conversion rate at which yield of the objective products becomes maximum; and Ccrs: the raw material conversion rate at which, when maximum temperature of the catalyst layer Zin is regarded as Tin, maximum temperature of the catalyst layer Zout is regarded as Tout, and the raw material conversion rate changes from Cmax to a raw material conversion rate other than Cmax, Tout>Tin; a wherein said catalyst has the formula:
MoaBibNicCodFefXgYhOx where Mo, Bi, Ni, Co and Fe represent molybdenum, bismuth, nickel, cobalt and iron, respectively; X represents at least one element selected from tungsten, antimony, tin, zinc, chromium, manganese, magnesium, silica, aluminum, cerium and titanium; Y represents at least one element selected from potassium, rubidium, thallium and cesium; and a, b, c, d, f, g, h and x represent the numbers of atoms of molybdenum, bismuth, nickel, cobalt, iron, X, Y and oxygen, respectively, such that a=12, b=0.1 to 7, c+d=0.5 to 20, f=0.5 to 8, g=0to 2, h=0.005 to 2, and x is a value determined by the oxidation state of the individual elements. |
