发明名称 |
METHOD FOR MANUFACTURING A TRICYCLODECANE MONO-METHANOL MONOCARBOXYLIC ACID DERIVATIVE |
摘要 |
<p>Provided is a method for manufacturing a tricyclodecane mono-methanol monocarboxylic acid derivative that can be used as a raw material for heat-resistant alicyclic polyesters and the like. The provided method is characterized in that a tricyclodecane mono-methanol monocarboxylic acid derivative represented by formula (III) is obtained as follows: the dicyclopentadiene represented by formula (I) is reacted with a formic acid compound in the presence of a catalytic system containing a ruthenium compound, a cobalt compound, and a halide salt, resulting in a tricyclodecane monocarboxylic acid derivative represented by formula (II), which is then hydroformylated. (In formulas (II) and (III), R represents hydrogen, a C1-5 alkyl group, a vinyl group, or a benzyl group.)</p> |
申请公布号 |
WO2011048851(A1) |
申请公布日期 |
2011.04.28 |
申请号 |
WO2010JP61582 |
申请日期 |
2010.07.08 |
申请人 |
HITACHI CHEMICAL COMPANY, LTD.;NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCEAND TECHNOLOGY;KAWAKAMI, HIROYUKI;TOMINAGA, KENICHI;SATO, KAZUHIKO |
发明人 |
KAWAKAMI, HIROYUKI;TOMINAGA, KENICHI;SATO, KAZUHIKO |
分类号 |
C07C67/347;C07B61/00;C07C69/757 |
主分类号 |
C07C67/347 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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