SYNTHESIS OF AQUEOUS, ANIONIC, AMINO ACRYLATE POLYMERS

摘要

Disclosed is a method of making aqueous, anionic amino polymers in water from olefinically unsaturated monomers including amine-containing monomers, but substantially without the inclusion of acid-group containing monomers. The polymerization of the amino polymer is carried out in the presence of a carboxy functional azo initiator dissolved in water by neutralization of acid groups present on the initiator. The polymer is useful in single-package or two-package coating compositions having pH above 7.0 that may be cured with polyisocyanates or polyepoxides.