发明名称 CONTINUOUS HYDROFORMYLATION OF OLEFINICALLY UNSATURATED COMPOUNDS
摘要 of the DiscLosure: OLefinicaLLy unsaturated compounds are continuousLy hydroformyLated under from 2 to 30 bar and at from 80 to 130.degree.C using, as a cataLyst, a rhodium compLex which contains, as Ligands, sparingLy voLatiLe compounds of the generaL formuLa I I where A is phosphorus, arsenic, antimony or bismuth and R1, R2 and R3 are each organic radicaLs by a method in which the hydroformyLation mixture consisting of Liquid and gaseous components is removed from the reactor and is subjected to reLativeLy high temperatures and/or reLativeLy Low pressures for a short time in a devoLatiLization coLumn, the mixture at the same time being separated into a gas phase and a Liquid phase, the gas phase is separated into the product ant the recycLe gas in a separator, and the recycLe gas and the Liquid phase from the devoLatiLization coLumn are recycLed to the reactor.
申请公布号 CA1254584(A) 申请公布日期 1989.05.23
申请号 CA19840445102 申请日期 1984.01.11
申请人 BASF AKTIENGESELLSCHAFT 发明人 KUMMER, RUDOLF;RICHTER, WOLFGANG;SCHWIRTEN, KURT;STOPS, PETER
分类号 B01J31/00;B01J31/22;B01J31/24;C07B61/00;C07C45/00;C07C45/50;C07C67/00 主分类号 B01J31/00
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