发明名称 |
Propylene diamine dimerisation, trimerisation - by heating with Gp. VIII metal catalyst, pref. with hydrogen |
摘要 |
<p>Prepn. of dipropylene triamine and tripropylene tetramine comprises condensing 1,2- or pref. 1,3-propylene diamine at 50-250 degrees C, pref. in presence of H2 and opt. with addn. of NH3. A Gp. VIII metal-contg. catalyst is used, including noble metals, and NH3 is produced during reaction. Higher polycondensates are decomposed to the dimers and trimers. At 25-200 bars H2 pressure and 160-200 degrees C conversions of ca 60% and sometimes ca 100% are obtd. for reaction times of 1-4 hrs. Good specificity for the dimer can be obtd. Prods. can be sepd. easily by distillation; very little prodn. of cyclic, branched or partially deaminated prods. occurs.</p> |
申请公布号 |
DE2540871(A1) |
申请公布日期 |
1977.03.24 |
申请号 |
DE19752540871 |
申请日期 |
1975.09.13 |
申请人 |
BASF AG |
发明人 |
GRAEFJE,HEINZ,DIPL.-CHEM.DR.;MESCH,WALTER,DIPL.-CHEM.DR.;WINDERL,SIEGFRIED,DIPL.-CHEM.DR.;MUELLER,HERBERT,DIPL.-CHEM.DR.;BOETTGER,GUENTER,DIPL.-CHEM.DR.;HOFFMANN,HERWIG,DIPL.-CHEM.DR. |
分类号 |
C07C209/64;(IPC1-7):C07C87/20 |
主分类号 |
C07C209/64 |
代理机构 |
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