发明名称 Herbicidal Compounds
摘要 The invention relates to pyrrolone compounds of the formula (I) wherein X, Rb, Rc, R1, R2 and R3 are as defined in the specification. Furthermore, the present invention relates to processes and intermediates for making compounds of formula (I), to herbicidal compositions comprising these compounds and to methods of using these compounds to control plant growth.;
申请公布号 US2016066574(A1) 申请公布日期 2016.03.10
申请号 US201414889948 申请日期 2014.05.01
申请人 SYNGENTA PARTICIPATIONS AG ;SYNGENTA LIMITED 发明人 Morris James Alan;Hachisu Shuji;Whittingham William Guy;Dalencon Anne Jaqueline;Boehmer Jutta Elisabeth;Phadte Mangala;Sonawane Ravindra;Longstaff Adrian;Dowling Alan John;Desson Timothy Robert;Pal Sitaram;Black Janice;Sasmal Swarnendu;Sawant Guruprasad Narashimh;Purumandla Srinivas Reddy;Ghorai Sujit Kumar
分类号 A01N43/80;A01N47/06;C07D413/14;C07D413/04 主分类号 A01N43/80
代理机构 代理人
主权项 1. A herbicidal compound of formula (I) wherein X is selected from S and O; Rb is selected from hydrogen, formyl, hydroxyl, halogen, nitro, cyano, C1-C8 alkyl, C1-C6 cyanoalkyl, C1-C6 haloalkyl, C1-C6 hydroxyalkyl, C2-C6 alkenyloxy C1-C6 alkyl, C1-C6 alkylthio, C1-C6 alkoxy, C1-C6 alkoxy C1-C6 alkyl, C1-C6 alkthio C1-C6 alkyl, C1-C6 cyanoalkoxy, C1-C6 haloalkoxy, C1-C6 alkoxy C1-C6 alkoxy, C2-C8 alkenyl, C2-C8 alkynyl, C2-C6 cyanoalkenyl, C2-C6 cyanoalkynyl, C2-C6 alkenyloxy, C2-C6 alkynyloxy, C2-C6 haloalkenyl, C2-C6 haloalkynyl, C2-C6 haloalkenyloxy, C2-C6 haloalkynyloxy, C1-C6 alkoxy C2-C6 alkenyl, C1-C6 alkoxy C2-C6 alkynyl, C1-C6 alkylsulfinyl, C1-C6 alkylsulfonyl, C1-C6 haloalkylthio, C1-C6 haloalkylsulfinyl, C1-C6 haloalkylsulfonyl, C1-C6 alkylsulfonyloxy, C1-C6 alkylcarbonyl, C1-C6 haloalkylcarbonyl, C2-C6 alkenylcarbonyl, C2-C6 alkynylcarbonyl, C2-C6 haloalkenylcarbonyl, C2-C6 haloalkynylcarbonyl, tri C1-C6 alkylsilyl C2-C6 alkynyl, C1-C6 alkylamido, a group R5R6N—, a group R5C(O)N(R6)—, a group R5S(C2)N(R6)—, a group R5R6NSO2—, a group R5R6NC(O) C1-C6 alkyl, a C6-C10 aryloxy group optionally substituted by from 1 to 3 groups independently selected from halogen, nitro, cyano, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 haloalkyl and C1-C3 haloalkoxy, a C6-C10 aryl C1-C3 alkyl group optionally substituted by from 1 to 3 groups independently selected from halogen, nitro, cyano, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 haloalkyl and C1-C3 haloalkoxy, a C6-C10 benzyloxy group optionally substituted by from 1 to 3 groups independently selected from halogen, nitro, cyano, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 haloalkyl and C1-C3 haloalkoxy, a C3-C6 heterocyclyl group optionally substituted by from 1 to 3 groups independently selected from C1-C4 alkyl, a C3-C6 cycloalkyl group optionally substituted with from 1 to 3 groups independently selected from halogen, cyano, C1-C6 alkoxy and C1-C6 alkyl and a C3-C6 cycloalkenyl group optionally substituted with from 1 to 3 groups independently selected from halogen, cyano, C1-C6 alkoxy and C1-C6 alkyl; Rc is selected from hydrogen, halogen, cyano, C1-C6 alkyl and C1-C6 haloalkyl; or Rb and Rc together with the carbon atoms to which they are attached form a 3-7 membered saturated or partially unsaturated ring optionally comprising from 1 to 3 heteroatoms independently selected from S, O and N and optionally substituted with from 1 to 3 groups independently selected from halogen, C1-C6 alkyl and C1-C6 haloalkyl; R1 is halogen and R2 is C1-C3 alkyl, C1-C3 alkoxy or —NR10R11 or R1 is C1-C3 alkoxy and R2 is halogen, C1-C3 alkyl or C1-C3 alkoxy, or R1 is C1-C3 alkyl and R2 is C1-C3 alkoxy; R3 is selected from halogen, hydroxyl, or any one of the following groups R5 and R6 are independently selected from hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, or R5 and R6 together with the carbon atoms to which they are attached form a 3-6 membered saturated or partially unsaturated ring optionally comprising from 1 to 3 heteroatoms independently selected from S, O and N and optionally substituted with from 1 to 3 groups independently selected from halogen and C1-C6 alkyl; R7 and R8 are independently selected from hydrogen, C1-C6 alkyl, C1-C6 haloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, a C5-C10 heteroaryl group which can be mono- or bicyclic comprising from 1 to 4 heteroatoms independently selected from N, O and S and optionally substituted with 1 to 3 groups independently selected from halogen, C1-C3 alkyl, C1-C3 haloalkyl and C1-C3 alkoxy, a C6-C10 aryl group optionally substituted with 1 to 3 groups independently selected from halogen, nitro, cyano, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 haloalkyl and C1-C3 haloalkoxy, or R7 and R8 together with the atoms to which they are attached form a 3-6 membered saturated or partially unsaturated ring optionally comprising from 1 to 3 heteroatoms independently selected from S, O and N and optionally substituted with from 1 to 3 groups independently selected from halogen or C1-C6 alkyl; R9 is selected from C1-C6 alkyl or benzyl optionally substituted with 1 to 3 groups independently selected from halogen, nitro, cyano, C1-C3 alkyl, C1-C3 alkoxy, C1-C3 haloalkyl and C1-C3 haloalkoxy; R10 is selected from H, C1-C6 alkyl, C1-C6 alkoxy-C1-C6 alkyl, C3-C6 cycloalkyl, C3-C6 cycloalkyl-C1-C6 alkyl, C2-C6 alkenyl and C2-C6 alkynyl; R11 is selected from H and C1-C6 alkyl, or an N-oxide or salt form thereof.
地址 Basel CH