发明名称 OLEFIN POLYMERIZATION CATALYST CONSTITUENT, OLEFIN POLYMERIZATION CATALYST, PRODUCTION OF OLEFIN POLYMER, AND USAGE OF ORGANIC SILICON COMPOUND
摘要 PROBLEM TO BE SOLVED: To obtain a constituent comprising a specific organosilicon compound, useful as an olefin polymerization catalyst and enabling the molecular weight distribution of an obtained polymer to be easily modified. SOLUTION: This constituent comprises an organosilicon compound expressed by the formula [wherein (n) is 1 or 2; R1 to R6 are each H, a halogen or a hydrocarbon and; R7 is a hydrocarbon], e.g. a di(substituted) cyclobutyldimethoxysilane or the like. When the objective constituent is applied to anα-olefin polymerization catalyst, it is obtained by contacting (A) a solid catalyst constituent containing a magnesium atom, a titanium atom, a halogen atom and an electron-donating compound and (B) an organoaluminum compound with (C) the above organosilicon compound. The constituent A is preferably obtained e.g. by reducing a titanium compound expressed by the formula Ti(OR8)aX4-1 a [wherein R8 is a 1-20C hydrocarbon; X is a halogen and; 0<(a)<=4] in the presence of an organosilicon compound having at least one Si-O bond.
申请公布号 JP2000309606(A) 申请公布日期 2000.11.07
申请号 JP20000044119 申请日期 2000.02.22
申请人 SUMITOMO CHEM CO LTD 发明人 KURIBAYASHI HIROSHI;SATO JUN
分类号 C08F4/654;C08F10/00;(IPC1-7):C08F4/654 主分类号 C08F4/654
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