| 摘要 |
Polyesteramides are polyamides of (i) at least one disecondary diamine in which at least one of the amino N atoms forms part of a heterocyclic group and in which the amino groups are separated by at least two carbon atoms, with (ii) at least one dicarboxylic acid: HOOC(CH2)nCOOH in which n is an integer from 2 to 10; the polyamide has incorporated in the macromolecular chain at least 5 but no more than 95 6-oxycaproyl units (-O(CH2)5 CO)- per 100 diamide plus 6-oxycaproyl units. The 6-oxycaproyl and diamide units form at least 90 out of every 100 units in the macromolecular chains; the polyesteramides have a reduced viscosity of at least 0.3 dl. per g. measured in n-cresol at 25 DEG C. The diamine may be piperazine or 4,41-bipiperidyl and the dicarboxylic acid may be adipic acid or sebacic acid. In a preferred polyesteramide the polyamide is formed from piperazine and adipic acid and the 6-oxycaproyl units form 60-85 mole per cent of the polymer. The polyesteramide may be prepared by reacting an ester generating compound (e.g. e -caprolactone) with: (i) at least one diamine and at least one dicarboxylic acid as defined above, or (ii) an alkane dicarboxylate salt obtained from the diamine and dicarboxylic acid as defined above, or (iii) at least one polyamide derived from the said diamines and dicarboxylic acids. Reaction is carried out (e.g. at 180-300 DEG C. in an inert atmosphere) until the polymer has a reduced viscosity of 0.3 dl. per g. at 25 DEG C. in m-cresol. Reaction may be in two stages: (i) the reactants are heated in a nitrogen atmosphere to obtain a uniform melt, and (ii) the melt obtained is reacted in a rapid flow of nitrogen until a product of the desired intrinsic viscosity is obtained. The polymers may be used in fabricating fibres and films and may also be useful as adhesives. |
