发明名称 |
Catalyst for single step conversion of glycerol to acrylic acid and process for the preparation thereof |
摘要 |
The present invention provides a process and a solid catalyst for oxydehydration of glycerol to acrylic acid with H2O2 under mild experimental condition at atmospheric pressure. The process provides a single step liquid phase selective oxidation glycerol to acrylic acid over nanocrystalline Cu supported α-MnO2 catalyst. The process provides glycerol conversion of 20-78% and selectivity of acrylic acid up to 86%. |
申请公布号 |
US9409847(B2) |
申请公布日期 |
2016.08.09 |
申请号 |
US201314072916 |
申请日期 |
2013.11.06 |
申请人 |
Council of Scientific & Industrial Research |
发明人 |
Bal Rajaram;Sarkar Bipul;Singha Rajib Kumar;Pendem Chandrashekar;Shankha Shubhra Acharyya;Ghosh Shilpi |
分类号 |
B01J23/889;B01J35/00;B01J37/00;C07C51/285;B01J37/03;B01J37/10 |
主分类号 |
B01J23/889 |
代理机构 |
Hudak, Shunk & Farine Co., LPA |
代理人 |
Hudak, Shunk & Farine Co., LPA |
主权项 |
1. Nanocrystalline Cu supported α-MnO2 catalyst comprising Cu in the range of 1 to 5 (wt %) MnO2 in the range of 99 to 95 (wt %) having a particle size in the range of 25 to 50 nm. |
地址 |
New Delhi IN |