Functional norbornanyl ester derivatives, polymers and process for preparing same

摘要

This invention relates to the new functional norbornanyl ester derivative and/or polymer compositions which are easily obtainable by reacting the Diels-Alder adduct of appropriate dienes and dienophiles with carboxylic acids. In particular, this invention relates to a new process for making cyclic chemical raw materials suitable for production coating, ink, adhesive, plasticizer, thermoplastic or thermosetting plastic and functional polymers.

主权项

1. A composition of polymer or oligomer comprising the units of norbornanyl ester represented by the general Formula-1: wherein, R1 is a hydrogen atom, a methyl, or a hydroxymethyl group and R2, R3, and R4 are the same or different from each other and are independently selected from the group consisting of hydrogen; halogen; hydroxyl; acid (—C(O)OH); ester (—C(O)ORa); formate (—OC(O)H); acid halide (—C(O)Z); aldehyde (—C(O)H); ketone (—C(O)Ra); nitro (—NO2); carboxamide (—C(O)NRaRb); amine (—NRaRb); silicone (—SiRaRbRc); cyano (—CN); isocyanate (—NCO); alkoxy (—ORa); phosphonate (—P(O)RaRb); unsubstituted or substituted C1-C100 alkyl group, unsubstituted or substituted C2-C100 alkenyl group, unsubstituted or substituted C2-C100 alkynyl group, unsubstituted or substituted C3-C100 cycloalkyl group, unsubstituted or substituted C6-C100 aryl group, provided that when it is substituted with one or more substituent groups, the substituent group may be carboxyl, hydroxyl, thiol, halogen, ester, amine, amide, imide, isocyanate, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, aryl, haloaryl, aralkyl, haloaralkyl, alkoxy, haloalkoxy, halocarbonyloxy, aryloxy, haloaryloxy, silyl, siloxy, glycidoxy, heterocyclo, carbonate, carboxylate, or quaternary ammonium; with the proviso that at least one of R2, R3, and R4 is a polar functional group containing at least one atom selected from the group consisting of oxygen, nitrogen, phosphorus, sulfur, silicon and boron; R2, R3, and R4 may be an acid anhydride group (—C(O)—O—C(O)—) or an imide group (—C(O)—NRd—C(O)—) formed by being bonded to each other when they are the functional groups; X represents oxygen, CH2, or CH2—CH2; k is an integer of 0 to 100; l is an integer 0 to 1; m and n both represent an integer 0 to 5; p is an integer 1 to 1000; Y is a bridge member selected from the group consisting of (—C(O)O—), (—R6—), (—R7C(O)O—), (—C(O)OR7O—), (—C(O)OR7OC(O)—), (—O—), (—OR7O—), (—R7OC(O)OR8—), (—R7C(O)OR8—), and (—R7C(O)R8—); Ra, Rb and Rc are independent hydrocarbyl or substituted hydrocarbyl, Rd is a hydrocarbyl group substituted with hydroxyl, alkoxy, alkenyl, amine, amide or imide group; Z is a halogen atom; R6, R7 and R8 are divalent organic groups and may be substituted or unsubstituted alkanes, alkenes, or cycloaliphatic groups.