发明名称 Process for the preparation of bis-benzazolyl compounds
摘要 The present invention provides a process for the preparation of a compound of formula (I) wherein Y represents -O-, -S- or -N(R2)-, R2 being hydrogen, C1-C10alkyl or aralkyl; Z represents a 2,5-furanyl, 2,5-thiophenyl, 4,4'-stilbenyl or a 1,2-ethyleny residue and R1 represents hydrogen, halogen, C1-C10alkoxyl, cyano, COOM or SO3M, M being hydrogen or an alkaline or alkaline earth metal, characterized by reacting a compound of formula (II) with a dicarboxylic acid of formula (III): HOOC-Z-COOH, or an ester thererof, Y, Z and R1 being as previously defined, in N-methylpyrrolidone or N,N-dimethylacetamide, in the presence of an acidic catalyst and, optionally, in the presence of a secondary solvent capable of removing water from the reaction mixture, which are useful as optical whitening agents for natural and synthetic materials.
申请公布号 US2003191320(A1) 申请公布日期 2003.10.09
申请号 US20030399312 申请日期 2003.04.16
申请人 ELIU VICTOR PAUL;HAUSER JULIA 发明人 ELIU VICTOR PAUL;HAUSER JULIA
分类号 C07B61/00;C07D235/20;C07D263/62;C07D263/64;C07D277/66;C07D405/14;C07D413/14;C07D417/14;(IPC1-7):C07D417/02;C07D413/02;C0743/02 主分类号 C07B61/00
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