发明名称 STYRENE-BASED FORMABLE RESIN PARTICLE AND ITS PRODUCTION
摘要 PROBLEM TO BE SOLVED: To obtain a styrene-based foamable resin particle not requiring aging, having slight change of a cell of a preexpanded styrene-based foamable resin particle, namely, hardly being affected by a storage condition and to provide a method for producing the styrene-based foamable resin particle. SOLUTION: This styrene-based foamable resin particle has <=100 voids/mm<2> at a distance of <=0.1mm from the surface in the radius direction on a section passing through the vicinity of the center of the styrene-based foamable resin particle within 0.1mm in the radius direction. In a method for producing the foamable resin particle by suspending a styrene-based monomer in an aqueous medium in the presence of a polymerization initiator and a suspending agent and adding a blowing agent to the suspension, an alkali metal persulfate or ammonium persulfate is added in such an amount as to become 0.5-30ppm based on the aqueous medium to the aqueous medium at the conversion ratio of the monomer of 0-30%. At a point of time when the conversion ratio of the polymerization is >=30%, an electrolyte is added in such an amount as to become 0.02-5.0mol/L based on the aqueous medium to the suspension to produce the objective styrene-based foamable resin particle.
申请公布号 JPH0971679(A) 申请公布日期 1997.03.18
申请号 JP19950227954 申请日期 1995.09.05
申请人 MITSUBISHI CHEM BASF CO LTD 发明人 SHINOZAKI HIROKI;TANAKA MASAYUKI;UEDA YONEZO;SUZUKI TAKANORI
分类号 C08F2/18;C08F12/00;C08J9/00;C08J9/20;(IPC1-7):C08J9/20 主分类号 C08F2/18
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