| 摘要 |
PCT No. PCT/EP93/03019 Sec. 371 Date Apr. 25, 1995 Sec. 102(e) Date Apr. 25, 1995 PCT Filed Oct. 29, 1993 PCT Pub. No. WO94/11408 PCT Pub. Date May 26, 1994Abstract of the Disclosure: Insoluble, only slightly swellable polymers containing amino groups, which can be obtained from popcorn polymers containing units of the structure <IMAGE> (I) where R and R1 are H or C1-C4-alkyl, by eliminating the group R-CO- from at least 2% of the incorporated units of the structure I, with the formation of units of the structure II <IMAGE> (II) a process for the preparation of the amino-containing popcorn polymers by polymerizing N-vinylcarboxamides and, if desired, other monoethylenically unsaturated monomers copolymerizable therewith with from 0.1 to 10% by weight, based on the monomers used in the polymerization, of a compound containing at least two ethylenically unsaturated non-conjugated double bonds as crosslinking agent, with exclusion of oxygen and polymerization initiators, to form popcorn polymers, and elimination of formyl groups from at least 2% of the copolymerized N-vinylcarboxamides, and the use of the resulting insoluble, only slightly swellable polymers containing amino groups as ion exchangers or adsorber resins for metal ions are described.
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