PERMEABLE MEMBRANES FOR ENHANCED GAS SEPARATION

摘要

PERMEABLE MEMBRANES FOR ENHANCED GAS SEPARATION Composite membranes are prepared by depositing a separation layer on an asymmetric support layer. The separation layer has a selectivity equal to or greater than that of the material of the asymmetric support layer for a desired gas separation. The support layer is desirably produced in non-asymmetric form, and exposed to an elevated temperature approaching the glass transition temperature of the support layer material under non-swelling conditions to modify the structure thereof to create asymmetry therein, before or after the deposition of the separation layer, and to increase its compaction resistance and collapse pressure. Such desirable properties are conveniently achieved on a repeatable basis, enhancing the uniformity and reliability of the treated support layer and of composite membranes produced therefrom, for use in gas separation operations. D-15509