摘要 |
- 1 - HOE 90/F 910 of the disclosure Process for the preparation of tertiary alcohols containing fluorine In the process described tertiary fluoroalcohols of the following formula in which Rf is a perfluoroalkyl radical having 4 to 20 carbon atoms, R1 is CH3 and R2 is CH3 or C2H5, are prepared by reacting perfluoroalkylethylenes of the formula Rf-CH=CH2 in which Rf has the meaning indicated, with excess isopropanol or excess sec.-butanol in the presence of free-radical initiators. |