发明名称 PURIFICATION OF AROMATIC VINYL COMPOUND
摘要 PURPOSE:To enablethe purification of a crude aromatic vinyl compound containing acetylene compound as an impurity, with simple procedure, at a low cost, by passing the crude vinyl compound through a catalyst layer containing one or more elements of tungsten and zinc, in the presence of steam at an elevated temperature. CONSTITUTION:An aromatic vinyl compound such as styrene, alpha-methylstyrene, vinyltoluene, divinylbenzene, etc. is heated at 150-400 deg.C, especially about 200-350 deg.C in the presence of steam, and passed through a catalyst layer containing tungsten and/or zinc (preferably the oxide of the element supported on a carrier such as silica, alumina, etc.) to remove the trace acetylene compound existing in thearomatic vinyl compound used as the raw material. A similar operation is effective also to the purification of a crude aromatic vinyl compound which is a mixture of an aromatic vinyl compound and an aromatic alkyl compound obtained by contacting an aromatic alkyl compound with a dehydrogenation catalyst in the presence of steam.
申请公布号 JPS61191626(A) 申请公布日期 1986.08.26
申请号 JP19850030263 申请日期 1985.02.20
申请人 ASAHI CHEM IND CO LTD 发明人 YAMAMOTO TADATSUGU;KINOSHITA JIRO
分类号 C07C7/167;B01J23/00;B01J23/06;B01J23/30;C07C1/00;C07C15/46;C07C67/00 主分类号 C07C7/167
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