| 摘要 |
A process for the production of coatings having scratch-resistant durable surfaces, in which there are used photocurable formulations comprising a surface-active photoinitiator, concentrated at the surface of the formulation, of formula (Ia), (Ib), (Ic) or (Id), wherein R and R1 are, for example, each independently of the other a radical of formula (II); R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others, for example, hydrogen; A-X, A1-X1-; unsubstituted or substituted C1-C12alkyl or phenyl; with the proviso that in formulae (Ia) and (Ib) at least one substituent A-X, A1-X1- is present in at least one of the radicals R and R1; and with the proviso that in formulae (Ic) and (Id) at least one of the radicals ); R2, R3, R4, R5, R6, R7, R5 and R9 is A-X, A1-X1-; A and A1 are each independently of the other a surface-active radical of formula (M) or Ao; n is, for example, a number from 1 to 1000 m is a number from 0 to 100; p is a number from 0 to 10 000; Ao is, for example, C6-C30alkyl; G1 and G2 are, for example, C1-C1alkyl; R18, R19, R2o, R22, R21, R23, R24, R25, R26 and R27 are, for example, C1-C18alkyl; and X and X1 are, for example, a single bond.
|
