发明名称 |
A SYNTHETIC METHOD OF A-KETOL UNSATURATED FATTY ACIDS |
摘要 |
A method of efficiently synthesizing an .alpha.-ketol unsaturated fatty acid having a double bond at the .beta.-position of the ketone moiety. The method is characterized by reacting a mono-substituted acetylene (2) with an epoxy compound (3) to synthesize a compound (4) and synthesizing an .alpha.-ketol unsaturated fatty acid (1) from the compound (4), as shown in the reaction formula (1). Reaction formula (1) (2) (3) (4) (1) (R1 is C1-18 alkyl or a C2 - 18 aliphatic hydrocarbon group having one to five double or triple bonds; R2 is a hydroxyl-protecting group; R3 is a carboxyl-protecting group; R is the same as R1, provided that when R1 contains one or more triple bonds, then R is an aliphatic hydrocarbon group in which the triple bonds have been converted to double bonds; and A is C1-18 alkylene.)
|
申请公布号 |
CA2397868(A1) |
申请公布日期 |
2002.08.08 |
申请号 |
CA20012397868 |
申请日期 |
2001.01.31 |
申请人 |
SHISEIDO CO., LTD. |
发明人 |
YOKOKAWA, YOSHIHIRO;YAMAMURA, SHOSUKE;KOBAYASHI, KOJI |
分类号 |
C07C51/36;C07B53/00;C07B61/00;C07C51/373;C07C51/377;C07C59/90;C07C67/31;C07C69/606;C07C69/732;(IPC1-7):C07C51/373 |
主分类号 |
C07C51/36 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|